N-Heterocycliccarbene相关论文
N-heterocyclic carbene-catalyzed reactions for the formation of aromatic compounds are reviewed.The reactions are subdiv......
Photoinduced E to Z isomerization of tetraphenylethylene derivatives within organometallic supramole
Isolation of E-1,2-bis(4-bromophenyl)-1,2-diphenyl-ethylene from the E/Z isomer mixture obtained by a McMurry coupling r......
Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadi
The methylation of alcohols is of great importance since a broad number of bioactive and pharmaceutical alcohols contain......
Phosphorescent Bis(N-heterocyclic carbene)Iridium(Ⅲ)Complexes as Mitochondria-Targeted Theranostic a
With a diverse range of mitochondrial targeted drugs currently in clinical trials,targeting mitochondria as a cancer the......
Reaction mechanisms of [2+2] cycloaddition of ketene and ketimine catalyzed by N-heterocyclic carben
N-heterocyclic carbenes (NHCs) have attracted great attention because of their high and special activity[1].Recently,NHC......
Phosphorescent Bis(N-heterocyclic carbene)Iridium(Ⅲ)Complexes as Mitochondria-Targeted Theranostic a
With a diverse range of mitochondrial targeted drugs currently in clinical trials,targeting mitochondria as a cancer the......
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Gold and Palladium Hetero-bis(NHC)Complexes:Characterizations,Correlations and Ligand Redistribution
Gold(Ⅰ)hetero-(NHC)complexes are given much less attention[1] despite the blooming of gold carbene chemistry.In this wo......
Transition-metal imido species are implicated as key intermediates in important transition-metal catalyzed transformatio......
N-heterocyclic carbene catalyzed enantioselective cascade reaction of enals has been developed with significant progress......
The spirocyclic oxindole-cylopentene skeletons featured in a large number of nature products have potential biological a......
Our research is focused on in-depth study of bioinspired proton transfer processes in catalysis that lead to discovery o......
Indolin-3-one with a quaternary stereocenter at the 2-position is frequently found as the privileged structure of numero......
Insights into the NHC-catalyzed Enantioselective and Chemoselective α-Fluorination of Aliphatic Alde
Based on the Wangs experiment,1 the reaction mechanism,stereoselectivity,and chemoselectivity on oxidative α-fluorinati......
NHC-Catalyzed Annulation of 1H-Indol-2-yl-malonate with 2-Bromoenals:Enantioselective Synthesis of P
Hydropyrido[1,2-a]indole is a core skeleton existing in a large class of naturally bioactive polycyclic indole alkaloids......
NHC-Catalyzed Asymmetric Synthesis of Functionalized Pyrrolo[3,2-c]quinolines and Trifluoromethyl Di
N-Heterocyclic carbenes (NHCs) have been widely employed as organocatalyst in synthetic transformation in recent decades......
N-Heterocyclic carbenes(NHCs)have played significant roles as a versatile class of ligands in organic catalysis,deliveri......
The knowledge on the formation,structure,and reactivity of low-coordinate 3d metal species is important for developing t......
Synthesis of a Mixed Silylene-Carbene Chelate Ligand from an N-Heterocyclic Silylcarbene Mediated by
N-heterocyclic carbenes(NHCs)represent one of the most widely utilized supporting ligands in transition metal(TM)chemist......
The field of supramolecular assemblies has developed rapidly in the last few decades,thanks in a large part to their div......
Carbene-catalyzed activation of cyclopropylcarbaldehydes for mannich reaction and δ-lactam formation
An N-heterocyclic carbene (NHC)-catalyzed enantioselective Mannich reaction of the remote 7-carbon of cyclopro-pylcarbal......
Over the past decades,N-heterocyclic carbenes (NHCs) have developed into a powerful kind catalysts for organic synth......
The introduction of N-heterocyclic carbenes(NHCs)as ligands for transition metals has generated many breakthroughs i......
以取代苄氯(1a~1c)为起始原料,与咪唑经氮烷基化反应制得苄基咪唑氯盐(2a~2c)；2a~2c与氧化银经原位去质子化反应合成了3种新型的氮......
以1,3-双(2,6-二异丙基苯基)咪唑鎓盐酸盐(IPrHCl,4a)或1,3-双[2,6-二(1-乙基丙基)苯基]咪唑鎓盐酸盐(IPent· HCl,5a),及Grubbs ......
While N-heterocyclic carbene(NHC)catalyzed electron-pair-transfer processes have been developed into an important tool f......
